The extraction process ( digestion) converts the aluminium oxide in the ore to soluble sodium aluminate, NaAlO 2, according to the chemical equation : Al 2 O 3 + 2 NaOH → 2 NaAlO 2 + H 2 O This treatment also dissolves silica, forming sodium silicate : 2 NaOH + SiO 2 → Na 2 SiO 3 + H 2 O The other components of Bauxite, however, do not dissolve.
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However, high alumina in the bauxite residue increases the flux and acid consumption. Therefore, alumina needs to be removed by alkali roasting prior to smelting in order to decrease the flux and acid consumption. The alkali roastingsmeltingleaching process allows recovery of aluminum, iron, titanium, and REEs from bauxite residue.
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Experimental Method. In this study, the recovery of precious metals from bauxite ore was examined by a twostage leaching process. The stages of this process were Stage I: Removing iron to a large extent and revealing the solubility conditions of titanium by treating the bauxite ore with oxalic acid, Stage II: Determining the recovery conditions of aluminum from the residue obtained after the ...
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The HCl leaching studies of bauxite indicated that as the concentration of HCl acid increases, the iron content reduces substantially, but at the same time, loss of alumina takes place. The change in bauxite colour from reddish brown to light colour indicated leaching of ore. It was found that bauxite of 300 µ size, leached with HCl of 25% ...
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The research on pressure leaching started in 1887. Karl Josef Bayer was the first one who proposed to leaching bauxite with sodium hydroxide solution at a temperature of 413453 K to obtain sodium ...
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Aluminum, which has the outstanding advantages of light weight and corrosion resistance, has a wide range of use in industries including aircraft, construction, automobile, and so on [].Unlike the iron direct extraction from iron ore, pure powder alumina should be firstly extracted from bauxite by alkali methods (Bayer process and sintering process), and then aluminum is produced through ...
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The reagent used to leach alumina from bauxite in Bayer's process is: Q. Assertion :Alumina is leached from bauxite using caustic soda Reason: Leaching is used when ore alone but not gangue is soluble in a suitable solvent. Q.
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Bauxite residue, known as red mud, is a byproduct of alumina production using the Bayer process. Currently, its total global storage amounts to over billion tons, including about 600 million tons in Russia. The total global storage of red mud occupies large areas, leading to environmental damage and increasing environmental risks. Moreover, it contains a significant amount of sodium ...
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In the extraction of aluminium, the significance of leaching is to concentrate pure alumina (AL2O3) from bauxite ore. Bauxite usually contains silica, iron oxide, and titanium oxide as impurities. In the process of leaching, alumina is concentrated by digesting the powdered ore with a concentrated solution of NaOH at 473523K and 3536 bar.
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Alkali process primarily contains sintering and hydrochemical process. In the sintering process, aluminacontaining materials are mixed with limestone and sintered, transforming silica into dicalcium silicate and alumina into calcium aluminate. Then, alumina can be separated from silica efficiently in followed sodium carbonate leaching process .
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Based on lime sintering method, a novel process of alumina production from lowgrade bauxite containing sulfur or fly ash is carried out in this paper. The phase of alumina transforms from 12CaO·7Al 2 O 3 (C 12 A 7) to 4CaO·3Al 2 O 3 ·SO 3 (C 4 A 3 S), whose alumina leaching property is better, through decreasing sinter temperature and time ...
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The leaching process with dilute HNO 3 was performed at pilot scale and optimized for the extraction of scandium from bauxite residue ( OchsenkühnPetropoulou et al., 2002 ). Xue et al. (2010) found that at a reaction temperature of 90 °C and an L/S ratio of 3:1, over 80% of the scandium in bauxite residue could be leached by H 2 SO 4.
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The process consists of the following steps: calcination of bauxite, leaching of calcined bauxite in hydrochloric acid, filtration of residue, crystallization of A1C1 3 .6 H 2 O, decomposition of AlCl 3 .6 H 2 O crystals to produce A1 2 O 3, regeneration of hydrochloric acid for recycle into the leaching step.
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The high volume of these tailings and problems with storage and disposal of them have created a motive to process and produce alumina from them. Several methods have been proposed for the extraction of alumina or some of the metals present in these tailings. One of the effective methods is to use a combination of roasting and leaching processes.
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A commercially successful process for extracting alumina from bauxite or clay must show a good extraction of highquality alumina and must include the recovery of much of the soda used. ... Ammonium sulphate formed in the last step is recycled and the aluminum hydroxide calcined to alumina. Sulphuric acid leaching process.Several acid ...
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Primary aluminum production is achieved by the combination of two metallurgical processes: (a) the Bayer process, which refines bauxite to metallurgicalgrade alumina (MGAl 2 O 3), and (b) the HallHéroult process, which produces aluminum metal by electrolytically reducing MGAl 2 O 3 in a cryolite bath. Increasing the sustainability of both these processes and of the entire primary ...
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Depending on the quality of bauxite, the amount of RM generated varies between 55 and 65% of the bauxite processed. Roughly Mg of RM are produced for each Mg of alumina and consequently ...
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Because the water leaching process does not consume additional reagents, it is economical. Still, this process is timeconsuming because longterm leaching and repeated dealkalization are necessary for the water leaching process. ... Red mud is a solid waste produced in the process of alumina prodn. from bauxite following the Bayer process ...
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The major commercial technology for the production of smelter grade alumina has conventionally been the Bayer process which converts bauxite ore, an aluminum containing ore which typically contains about 50 % Al 2 O 3, into smelter grade alumina that contains over % Al 2 O potential source of aluminum that is receiving renewed attention is coal fly ash (CFA), which is a by ...
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To prevent this, a desilication process to reduce the amount of silicon in solution is conducted prior to precipitating hydrated alumina. In the Bayer process, bauxite ores are pressure leached at a high temperature (100250 °C) using sodium hydroxide solution. The leachate solution is then cooled and seeded to precipitate alumina hydrates.
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The doublecycle process is pressure leaching of hydrochloric acid—extraction and separation of leaching solution—direct pyrolysis of aluminum chloride solution for producing alumina. Firstly, highiron bauxite is used as raw material to extract aluminum and iron elements in it by hydrochloric acid leaching.
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The excessive production of bauxite residue (red mud) in the Bayer process is one of the major challenges amongst alumina producers. The Pedersen process is known as a combination of smelting reduction of bauxite and leaching treatment of the produced slag for alumina production, and the process also produces an inert bauxite residue (grey mud), which is more suitable for further processing ...
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In some cases, the impure ore is treated with a suitable reagent, such as an acid or a base. Because of that, the ore particles dissolve due to leaching, but the gangue impurities do not react. This process is a solidliquid extraction process, and the following example illustrates the procedure of this process: Leaching of alumina from bauxite:
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Literature leaning towards Bayer process efficiency often targets leaching conditions in Bayer digestion and selectivity of aluminum precipitation species for activated alumina recovery, and from the byproduct valorisation, the sintering of bauxite residues for the recovery of aluminum and sodium [25,26,27,28]. The scope of this work will be ...
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Introduction. Bauxite is the major ore for aluminum production. Alumina is extracted from bauxite by the Bayer process. The waste slurry generated in this process is called red mud and its solid fraction is called bauxite residue. About 12 metric tonnes of bauxite residue is generated for each tonne of alumina produced (Kumar et al., 2006).
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This study investigates applying the principles of the longdiscontinued Pedersen process as a possible route for producing metallurgical grade alumina from lowgrade and secondary feed materials. The investigation focused on the hydrometallurgical steps in the process, namely leaching, desilication, and precipitation, and adapting it to valorize bauxite residue. The test material used was a ...
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A material supplier from Belgium would like to produce limestone powder for his custome...
India is rich in various mineral resources and it is an important mineral processing market
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